Search results for "Materials Science | Hot Paper"
showing 7 items of 1457 documents
Analyse tridimensionnelle des micromécanismes de transfert de charge dans les composites fibres/résine
2005
Environmental remediation using nanomaterial as adsorbents for emerging micropollutants
2023
Water shortage and scarcity are issues of global concern. Water pollution caused by organic micropollutants further aggravates the problem, by rendering an already scarce resource unfit for human consumption. The existing conventional wastewater treatment methods and infrastructure were not designed to eliminate micropollutants. Therefore, their inefficiencies call for modern methods for removing emerging micropollutant residues such as Active Pharmaceutical Ingredients (APIs), Endocrine Disrupting Compounds (EDCs), personal care products and pesticides. The use of nanomaterials, for the abatement of micropollutants in water is gaining traction in recent years, due to the abundance of susta…
Efficient zinc incorporation into hydroxyapatite through crystallization of an amorphous phase could extend the properties of zinc apatites
2013
Photoluminescence properties of S2 molecule trapped in Melanophlogite
2015
We studied the photoluminescence properties of a sample of SiO2-clathrate Melanophlogite, a crystalline microporous material which is found in nature as a rare mineral. Upon β irradiation, the material displays an intense light emission under near-UV illumination. We studied in detail this optical activity by steady-state and time-resolved photoluminescence measurements as a function of temperature. The spectroscopic properties we find can be ascribed to a population of quasi-free molecules trapped within each of the two different types of cage available in the structure of this clathrate, although the spectroscopic properties of the guest molecules are affected by their interactions with t…
Desymmetrization of Prochiral Cyclobutanones via Nitrogen Insertion: A Concise Route to Chiral γ‐Lactams
2021
Abstract Asymmetric access to γ‐lactams is achieved via a cyclobutanone ring expansion using widely available (1S,2R)‐1‐amino‐2‐indanol for chiral induction. Mechanistic analysis of the key N,O‐ketal rearrangement reveals a Curtin–Hammett scenario, which enables a downstream stereoinduction (up to 88:12 dr) and is corroborated by spectroscopic, crystallographic, and computational studies. In combination with an easy deprotection protocol, this operationally simple sequence allows the synthesis of a range of optically pure γ‐lactams, including those bearing all‐carbon quaternary stereocenters. In addition, the formal synthesis of drug molecules baclofen, brivaracetam, and pregabalin further …
Влагопоглощение органопластиком и его влияние на физико-механические свойства материала
1990
Advisor: Максимов Р. Д., Янсон Ю. О.